If you go with interpersonal drama, no episode beats �The City on the It horror Pittsburgh Steelers 2022 shirt and I love this Edge of Forever�. This episode is not so much about the Star Trek Federation as it is pure science fiction. Good intentions facing exploiters- a classic paradox of good v. evil. If you could go back in time, what choices would you make differently than the path you find yourself walking? It has love, drama, and scenes of action, written by Harlan Ellison, an excellent science fiction writer. The episode won a Writer�s Guild award and a Hugo for dramatic presentation. The guest star, a young Joan Collins, was superb. Probably the best guest star role of the series. The special effects were well presented and the story resonated with viewers. I personally was not impressed with Shatner�s biting of his fist at the end to signify his pain and loss, but the rest of his performance was well received.
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I like all three of these episodes for their own unique stories but if forced to choose I must go with �Balance of Terror� just beating out �City on the It horror Pittsburgh Steelers 2022 shirt and I love this Edge Forever.� This is not based on a connection to the world of Trek, or because it was early in the show�s production. It is based simply on my personal choice. When I have not watched TOS for awhile and I pull up the shows on a streaming service or peruse my DVD�s, I never pass up Balance of Terror. I can watch it again and again. There�s a bit more to it, IMO, that the other answers have said: Unlike a modern military, star fleet officers have considerable legal jurisdiction in areas outside the core systems; they are, in effect, the entire executive branch of the government, including military, but also medical, law enforcement, judicial, civil services�